Copper/iron co-catalyzed alkoxycarbonylation of unactivated alkyl bromides
نویسندگان
چکیده
منابع مشابه
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Several examples on Pd-catalysed carbonylation of methyl C(sp3)-H bonds with gaseous CO via Pd(II)/Pd(0) catalysis have been reported. However, methylene C(sp3)-H carbonylation remains a great challenge, largely due to the lack of reactivity of C-H bonds and the difficulty in CO migratory insertion. Herein, we report the stereoselective alkoxycarbonylation of both methyl and methylene C(sp3)-H ...
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ژورنال
عنوان ژورنال: Communications Chemistry
سال: 2018
ISSN: 2399-3669
DOI: 10.1038/s42004-018-0039-6